Electronic perturbation-promoted interfacial pathway for facile C–H dissociation

Pt-based catalysts have been extensively employed in catalytic propane dehydrogenation (PDH) processes, playing a crucial role in propylene production. However, monometallic Pt catalysts often exhibit inferior propylene selectivity due to the hydrogenolysis, rapid deactivation from coke deposits, and nanoparticle sintering. To address these challenges, various metals (Sn, Zn, Ga, Co, etc.) have been introduced to enhance the selectivity and stability of Pt-based catalysts.